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Table 3 Chronic ecotoxicity of microplastic particles towards R. subcapitata in the 72 h growth inhibition assay

From: Polymers of low concern? Assessment of microplastic particles used in 3D printing regarding their toxicity on Raphidocelis subcapitata and Daphnia magna

Application / Purpose

Polymer

Hypotheses for testing

EC50 72 h

[mg/L]

Agglomeration

Result

Selective Laser Sintering (SLS) and variations of the same polymer backbones

TPU_ester_arom

• Thermoplastic vs. cross-linked

• Ester vs. Ether backbone

• aromatic vs. aliphatic soft segment

• Influence of particle size as well as of polydispersity

> 100

No

No impact of linking, backbone, aromaticity and state on R. subcapitata toxicity

No impact of particle size in the µm-range on R. subcapitata toxicity

TPU_ether_arom

> 100

No

TPU_ester_aliph

> 100

No

TPU_ether_aliph

> 100

No

PU_binder_aromatic 1 C

> 100

No

PU_binder_aromatic 2 C

> 100

No

PA-6

> 100

No

Benchmark

HDPE_broad_distribution

• Influence of particle size as well as of polydispersity

> 100

Minor

No impact of polydispersity on R. subcapitata toxicity

PMMA (monodisperse)

> 100

No

No impact of particle size in the nm-range on R. subcapitata toxicity